Si‐bearing metal and niningerite in Almahata Sitta fine‐grained ureilites and insights into the diversity of metal on the ureilite parent body

A detailed mineralogical and chemical study of Almahata Sitta fine‐grained ureilites (MS‐20, MS‐165, MS‐168) was performed to shed light on the origin of these lithologies and their sulfide and metal. The Almahata Sitta fine‐grained ureilites (silicates <30 μm grain size) show textural and chemical evidence for severe impact smelting as described for other fine‐grained ureilites. Highly reduced areas in Almahata Sitta fine‐grained ureilites show large (up to ～1 mm) Si‐bearing metal grains (up to ～4.5 wt% Si) and niningerite [Mg_>0.5,(Mn,Fe)_<0.5S] with some similarities to the mineralogy of enstatite (E) chondrites. Overall, metal grains show a large compositional variability in Ni and Si concentrations. Niningerite grains probably formed as a by‐product of smelting via sulfidation. The large Si‐Ni variation in fine‐grained ureilite metal could be the result of variable degrees of reduction during impact smelting, inherited from coarse‐grained ureilite precursors, or a combination of both. Large Si‐bearing metal grains probably formed via coalescence of existing and newly formed metal during impact smelting. Bulk and in situ siderophile trace element abundances indicate three distinct populations of (1) metal crystallized from partial melts in MS‐20, (2) metal resembling bulk chondritic compositions in MS‐165, and (3) residual metal in MS‐168. Almahata Sitta fine‐grained ureilites developed their distinctive mineralogy due to severe reduction during smelting. Despite the presence of E chondrite and ureilite stones in the Almahata Sitta fall, a mixing relation of E chondrites or their constituents and ureilite material in Almahata Sitta can be ruled out based on isotopic, textural, and mineral‐chemical reasons.     

The effect of crystallization time on plagioclase grain shape in dolerites

The average aspect ratio of plagioclase, measured in thin section, varies systematically through dolerite sills, with a symmetrical “M”-shaped profile observed in sills thinner than ~200 m. Thicker sills show the same marginal reversal at the base, but average aspect ratios appear to continue increasing towards the top, creating an “S”-shaped profile. A distorted “M”-shaped profile is visible in the stratigraphic variation of plagioclase average aspect ratios in the prehistoric Makaopuhi lava lake, with the centre of the “M” in the olivine-enriched horizon close to the base of the lake. Higher overall values of average aspect ratio are observed in thin sills compared to thicker sills, demonstrating that the plagioclase in more slowly crystallized bodies is more equant than that in more rapidly crystallized bodies. There is a strong correlation between the plagioclase average aspect ratio in the central parts of the sills and the crystallization time calculated using a simple one-dimensional thermal model assuming conductive cooling. The cause of the marginal reversals in average aspect ratio is not well understood, but may result from early grain impingement in the developing crystal mushy layer.     

Multi-Wavelength Analysis of the 29 September 2002 M2.6/2N Flare

Using TRACE EUV 171 Å line, Hα line, Zürich radio, RHESSI, and HXRS observations the 29 September 2002 flare (M2.6), which occurred in AR NOAA 0134, was analyzed. Flaring structures were compared with a potential magnetic field model (field lines and quasi-separatrix layers) made from SOHO/MDI full-disk magnetogram. Series of high-resolution SOHO/MDI magnetograms and TRACE white-light images were used to find changes in the active region at the photosphere during the flare. The flare began with a rising of a small dark loop followed by the flare brightening observed in 171 Å with TRACE and Hα lines. In radio wavelengths, first type III bursts were observed 5 min prior to the start of hard X-ray emission, indicating a pre-flare coronal activity. The main hard X-ray emission peak (at 06:36 UT) was associated with the second type III burst activity and several slowly negatively drifting features, all starting from one point on the radio spectrum (probably a shock propagating through structures with different plasma parameters). After this time a huge loop formed and three minutes later it became visible in absorption both in Hα and 171 Å EUV lines. The phase of huge dark loop formation was characterized by long-lasting, slowly negatively drifting pulsations and drifting continuum. Finally, considering this huge loop as a surge an evolution of the event under study is discussed.     

Orthopyroxene oikocrysts in the MG1 chromitite layer of the Bushveld Complex: implications for cumulate formation and recrystallisation

Two typical mineral textures of the MG 1 chromitite of the Bushveld Complex, South Africa, were observed; one characterised by abundant orthopyroxene oikocrysts, and the other by coarse-grained granular chromitite with only minor amounts of interstitial material. Oikocrysts form elongate clusters of several crystals aligned parallel to the layering, and typically have subhedral, almost chromite-free, core zones containing remnants of olivine. The core zones are surrounded by poikilitic aureoles overgrowing euhedral to subhedral chromite chadacrysts. Chromite grains show no preferred crystal orientation, whereas orthopyroxene grains forming clusters commonly share the same crystallographic orientation. Oikocryst core zones have lower Mg# and higher concentrations of incompatible trace elements compared to their poikilitic aureoles. Core zones are relatively enriched in REE compared to a postulated parental magma (B1) and did not crystallise in equilibrium with the surrounding minerals, whereas the composition of the poikilitic orthopyroxene is consistent with growth from the B1 magma. These observations cannot be explained by the classic cumulus and post-cumulus models of oikocryst formation. Instead, we suggest that the oikocryst core zones in the MG1 chromitite layer formed by peritectic replacement of olivine primocrysts by reaction with an upwards-percolating melt enriched in incompatible trace elements. Poikilitic overgrowth on oikocryst core zones occurred in equilibrium with a basaltic melt of B1 composition near the magma-crystal mush interface. Finally, adcumulus crystallisation followed by grain growth resulted in the surrounding granular chromitite.     

Do agonistic behaviours bias baited remote underwater video surveys of fish?

Marine environments require monitoring to determine the effects of impacts such as climate change, coastal development and pollution and also to assess the effectiveness of conservation measures. Marine protected areas (MPAs) are being established globally and require periodic monitoring to determine whether their objectives are being met. Baited underwater video systems are becoming a popular method for monitoring change within protected fish populations, because they are less damaging to habitats than bottom trawling and allow for more statistical powerful comparisons to determine spatial and temporal patterns in the relative abundances, lengths and biomass of demersal and pelagic fishes. However, much remains uncertain about how interactions between the fish and bait and between the fish themselves affect the results obtained. Agonistic behaviours are frequently observed around the bait of the camera and potentially bias fish density estimates by altering the number and size classes seen at cameras. Here we counted the number of agonistic behaviours between pink snappers (Pagrus auratus), the size of fish involved and whether the fish left the field of view following such behaviours. The study consisted of 20 baited underwater video deployments inside a New Zealand marine reserve and 20 in adjacent open areas. We observed a significant relationship between the peak number of fish observed at the camera and the total number of agonistic behaviours, as well as the number of both aggressor and subordinate fish leaving the camera field of view following interactions. The slope of the latter relationship and thus the absolute numbers of fish leaving were higher for subordinate fish. As subordinates were significantly smaller than aggressors, the apparent size frequency distribution is likely skewed away from smaller size classes. The staying time of the fish and thus the maximum number of fish present at the camera will be reduced by agonistic behaviours and the absolute magnitude of this effect appears to be greater at high fish densities. Our results suggest that an overall effect of these phenomena is to underestimate the differences in abundance between MPAs and open areas, but also to overestimate differences in average size.     

A comparison of suspended particulate matter from nepheloid and clear water

Particulate matter from the nepheloid layer and from regions of clearer water have been examined under the light microscope to determine particle concentration, size and composition. The total count of suspended particles is a basic difference between water samples from nepheloid layers of the North American and Brazil basins, and samples from the clearer water over the Mid-Atlantic Ridge in both the North and South Atlantic. The nepheloid layer of the North American Basin has four times, and the Brazil Basin three times the particle density of clearer water over the mid-ocean ridge. A greater percentage of particles of < 2 μ size prevails in nepheloid water ranging from 85–96% as compared to a range of 76–87% in the clear water. Non-opaque mineral grains form the major constituent.     

Multi-Wavelength Analysis of High-Energy Electrons in Solar Flares: A Case Study of the August 20, 2002 Flare

A multi-wavelength spatial and temporal analysis of solar high-energy electrons is conducted using the August 20, 2002 flare of an unusually flat (γ₁ = 1.8) hard X-ray spectrum. The flare is studied using RHESSI, Hα, radio, TRACE, and MDI observations with advanced methods and techniques never previously applied in the solar flare context. A new method to account for X-ray Compton backscattering in the photosphere (photospheric albedo) has been used to deduce the primary X-ray flare spectra. The mean electron flux distribution has been analysed using both forward fitting and model-independent inversion methods of spectral analysis. We show that the contribution of the photospheric albedo to the photon spectrum modifies the calculated mean electron flux distribution, mainly at energies below ∼100 keV. The positions of the Hα emission and hard X-ray sources with respect to the current-free extrapolation of the MDI photospheric magnetic field and the characteristics of the radio emission provide evidence of the closed geometry of the magnetic field structure and the flare process in low altitude magnetic loops. In agreement with the predictions of some solar flare models, the hard X-ray sources are located on the external edges of the Hα emission and show chromospheric plasma heated by the non-thermal electrons. The fast changes of Hα intensities are located not only inside the hard X-ray sources, as expected if they are the signatures of the chromospheric response to the electron bombardment, but also away from them.     

Standardized uncertainty analysis for hydrometry: a review of relevant approaches and implementation examples

Abstract

The water-centric community has continuously made efforts to identify, assess and implement rigorous uncertainty analyses for routine hydrological measurements. This paper reviews some of the most relevant efforts and subsequently demonstrates that the Guide to the expression of uncertainty in measurement (GUM) is a good candidate for estimation of uncertainty intervals for hydrometry. The demonstration is made by implementing the GUM to typical hydrometric applications and comparing the analysis results with those obtained using the Monte Carlo method. The results show that hydrological measurements would benefit from the adoption of the GUM as the working standard, because of its soundness, the availability of software for practical implementation and potential for extending the GUM to hydrological/hydraulic numerical simulations.

Editor D. Koutsoyiannis

Citation Muste, M., Lee, K. and Bertrand-Krajewski, J.-L., 2012. Standardized uncertainty analysis for hydrometry: a review of relevant approaches and implementation examples. Hydrological Sciences Journal, 57 (4), 643–667.     

Anomalous high amplitude ratios of P5KP/PKPab and P4KP/P(S)cP observed globally around 1 Hz

Amplitude ratio of 30 short-period conspicuous P5KP and PKPab phases from five intermediate depth or deep events in Fiji-Tonga recorded at European stations around 150° distance shows a mean value two to three times the ratio of the synthetic amplitudes obtained by the normal-mode theory (and ak135 model) or by full-wave theory (and PREM). There is a large variance in the results, also observed in five amplitude ratios from one event in Argentina observed at temporary stations in China around 156°. Global recordings of three major deep earthquakes in Fiji, Bonin, and Western Brazil observed at ASAR, WRA, and ZRNK arrays, at 59 North America stations and at six South Pole stations displayed conspicuous P4KP and PcP (or ScP) phases. The amplitude ratio values of P4KP vs P(S)cP are sometimes almost one order of magnitude larger than the corresponding values of the synthetics. In both cases, arrival times and slowness values (corrected for ellipticity and station elevation) at the distances up to 23° beyond the A cutoff point predicted by ray theory match both the synthetics, suggesting the observations are the AB branch of PmKP (m?=?4, 5) around 1 Hz. In disagreement to ray theory, no reliable BC branch is observed neither on the recordings nor on the normal-mode synthetics. The high amplitude ratio values cannot be explained by realistic perturbations of the velocity or attenuation values of the global models in the proximity of the core-to-mantle boundary (CMB). We speculate that the focusing effects and/or strong scattering most likely associated to some anomalous velocity areas of the lowermost mantle are responsible for that. The results suggest limitations of the previous evaluations of the short-period attenuation in the outer core from PmKP amplitudes (m?≥?3), irrespective of the fact that they are obtained by using ray theory, normal-mode or full-wave synthetics. Attempts to use PmKP arrival times in order to refine velocity structure in the proximity of CMB should be also regarded with care if the propagation times have been computed with ray theory.